A new interesting class of polyamides of diarylidenecycloalkanone containing azo
groups in the polymer backbone 6a-d was synthesized by a solution polycondensation
reaction of bis 2-aminoarylidene monomers 3a,b with 4,40-azodibenzoyl dichlorides and
3,30-azodibenzoyl dichlorides in NMP as a solvent, using anhydrous LiCl as a catalyst
at room temperature. The model compounds 4, 5 were synthesized by the interaction of
one mole of bis 2-aminoarylidene monomers 3a,b with two moles of benzoyl chloride
using anhydrous LiCl as a catalyst in NMP at room temperature. The resulting polymers
were characterized by elemental and spectral analyses, besides solubility and
viscometry measurements. The thermal properties of those polymers were evaluated
by TGA, DTG and DTA measurements and correlated to their structural units.
X–ray analysis of the polymers showed that polyamides based on para-azo linkage have
a higher degree of crystallinity than those based on meta-azo linkage in the region
2h¼5
60. In addition, the morphological properties of selected examples were tested
by SEM.