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Structure and magnetic properties of flux grown single crystals of Co3−xFexSn2S2 shandites

Research Authors
Mohamed A. Kassem, Yoshikazu Tabata, Takeshi Waki, Hiroyuki Nakamura
Research Abstract

We report a successful single crystal growth of the shandite-type half-metallic ferromagnet Co3Sn2S2, and its Fe-substituted compounds, Co3−xFexSn2S2, by employing the flux method. Although Fe3Sn2S2 is unstable phase, we found that using the self Sn flux enables us to obtain single phase crystals up to x=0.53. The chemical composition of the grown plate-shaped single crystals was examined using wavelength-dispersive X-ray spectroscopy. The shandite structure with R
̅
3̅m symmetry was confirmed by powder X-ray diffraction and the crystal structure parameters were refined using the Rietveld method. Magnetization measurements show suppression of the ferromagnetic order upon Fe-substitution , as well as in other substituted systems such as In- and Ni-substituted Co3Sn2S2. The almost identical magnetic phase diagrams of the Fe- and In-substituted compounds indicate that the electron number is dominantly significant to the magnetism in the Co-based shandite.

Research Department
Research Journal
Journal of Solid State Chemistry
Research Publisher
Science Direct
Research Rank
1
Research Vol
Vol. 233
Research Website
http://www.sciencedirect.com/science/article/pii/S0022459615301924
Research Year
2016
Research Pages
pp. 8-13