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Influence of anodizing voltage and electrolyte concentration on Al-1wt% Si thin films anodized in H2SO4

Research Authors
AlaaMAbd-Elnaiem,Gh Abbady, Dalia Ali, T B Asafa
Research Abstract

Porous anodic alumina (PAA) templates have been extensively studied due to their unique morphology and
extensive applications.The fabrication of PAAcan bemodulated to achieve a self-ordered pore structure
with desired pore size and interpore separation.PAAthin film templateswere fabricated fromsilicon doped
aluminumfilm,Al-1wt%Si, based on one-step anodization method at 22 °C. Effects of anodizing potential
(10–20V) as well as sulfuric acid concentrations (0.6–1.8M) on current density, interpore distance,
anodization rate, and volume expansion were evaluated.The results indicated that current density increased
largely exponentially with a concentration of the electrolyte at a given anodizing voltage. In addition, distinct
andwell-ordered pores were obtained for anodization conducted at 15Vand 20 V. The volume expansion
factor is proportional to the applied voltage. At 1.8Msulfuric acid, the expansion factor increases with pore
regularity with 1.4 considered as the transition point.Theminimumcurrent density (2.1±0.15mAcm−2)
was observed at theminimumanodizing condition (0.6M, 10V).Also,maximumanodizing condition
(1.8M, 20V) resulted in the highest current density of 34±4mAcm−2.As expected, anodization time
decreaseswith an increase in both anodization voltage and electrolyte concentration.

Research Department
Research Journal
Materials Research Express
Research Member
Research Publisher
IOP Publishing Ltd
Research Rank
1
Research Vol
6
Research Website
https://doi.org/10.1088/2053-1591/ab2848
Research Year
2019
Research Pages
086468