To satisfy global energy demands and decrease the level of atmospheric greenhouse gases, alternative clean energy sources are required. Hydrogen is one of the most promising clean energy sources due to its high chemical energy density and near-zero greenhouse gas emissions. A single alloyed phase of Pd/Pt nanoclusters as quantum dots (QDs) was prepared and loaded over Co3O4 nanoparticles with a low loading percentage (1 wt.%) for hydrogen generation from the hydrolysis of NaBH4 at room temperature. L-glutathione (SG) was used as a capping ligand. It was found that the single alloy catalyst (Pd0.5–Pt0.5)n(SG)m/Co3O4 caused a significant enhancement in hydrogen generation in comparison to the monometallic clusters (Pdn(SG)m and Ptn(SG)m). Moreover, the Pd/Pt alloy showed a positive synergistic effect compared to the physical mixture of Pd and Pt clusters (1:1) over Co3O4.
ملخص البحث
تاريخ البحث
قسم البحث
مجلة البحث
Scientific Reports
المشارك في البحث
سنة البحث
2022