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The effect of composition on the structure, optical, and room-temperature ferromagnetic properties of hydrothermally synthesized (ZnSn)1-xCuxO nanocomposites

مؤلف البحث
A.G. Abd-Elrahim, A. Sedky, N. Afify, Ahmed Abbas
ملخص البحث

(ZnSn)1-xCuxO nanocomposites (NCs) with nanorods and nanosheet morphologies were synthesized by a facile hydrothermal technique. (ZnSn)1-xCuxO NCs exhibited a gradual band gap redshift from UV to visible spectral region with increasing Cu-content. The room temperature magnetic hysteresis loop indicated the improvement of room temperature ferromagnetic (RTFM) behavior of (ZnSn)1-xCuxO NCs compared with nanostructured ZnSnO NCs induced by the exchange interaction of Cu-bound polarons with the localized spins and free carriers. The (ZnSn)60Cu40O NCs exhibited the highest saturation magnetization (Ms) of 0.539 emu·g−1. Further increase in Cu-content resulted in the deterioration of crystalline domains and the reduction of Ms to 0.259 emu·g−1. This behavior revealed that the electronic and magnetic properties of (ZnSn)1-xCuxO NCs were so sensitive to the dopant concentration that need to be utilized for improving their performance as good candidate NCs for spintronic applications.

تاريخ البحث
قسم البحث
المشارك في البحث
الناشر
Elsevier
تصنيف البحث
International Journal
عدد البحث
674
موقع البحث
https://doi.org/10.1016/j.physb.2023.415568
سنة البحث
2024
صفحات البحث
415568