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Cooperative effects due to Zn–Sn replacement by Co-ions on the optical and magnetic properties of (ZnSn)1- xCoxO nanocomposites

مؤلف البحث
A. Sedky; N. Afify; Ahmed Abbas; A. G Abd-Elrahim
ملخص البحث

In the present study, the structural, optical, and magnetic properties of (ZnSn)1-xCoxO nanocomposites (NCs) were reported. The transmission electron microscope (TEM) images of ZnSnO NCs showed mixed nanorods and nanosheets morphologies that completely transformed to mostly nanocubes with Co-ions incorporation. The optical band gap (Eg) of nanostructured ZnO, SnO, and ZnSnO NCs was 3.2, 4.5, and 3.9 eV, respectively. The estimated Eg value of all (ZnSn)1-xCoxO NCs was lower than the undoped ZnSnO NCs. The nanostructured ZnO revealed poor room-temperature ferromagnetic (RTFM) behavior whereas nanostructured SnO exhibited paramagnetic behavior at low magnetic field strength followed by diamagnetic behavior at high magnetic field strength. The (ZnSn)1-xCoxO NCs exhibited strong improvement in the RTFM, where the hybrid (ZnSn)60Co40O NCs exhibited the highest saturation magnetization (Ms) of 2 emu·g−1. This value was 5-times higher than the undoped ZnSnO NCs and 2-orders of magnitude higher than the pure ZnO phase. However, with increasing Co-content up to 50 %, the Ms was reduced to 1.16 emu·g−1 demonstrating the corruption of RTFM. The present study indicated the importance of composition utilization for tuning physical properties of (ZnSn)1-xCoxO NCs and improving the performance of these NCs in optoelectronic and spintronics applications.

تاريخ البحث
قسم البحث
مجلة البحث
Materials Chemistry and Physics
الناشر
Elsevier
تصنيف البحث
International Journal
عدد البحث
313
موقع البحث
https://doi.org/10.1016/j.matchemphys.2023.128776
سنة البحث
2024
صفحات البحث
128776