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Investigations of Co(II), Ni(II) and Cu(II) –(2,2’:6’,2”- Terpyridine)Complexes with Sulfur Donor Ligands.

Research Authors
A.M. Hammam, S.A. Ibrahim, M.A. El-Gahami and D.M. Fouad
Research Abstract

The ‘complexes as metal’ strategy has been used to prepare new mixed ligand complexes containing Co(II), Ni(II) and Cu(II) terpyridine (terpy) with dithiooxamide (dto) and thiosemicarbazide (tsc). Characterization of the complexes has been accomplished by elemental analysis, molar conductance, thermal analysis, as well as electronic and IR spectral measurements. It is deduced that the coordination mode of the terpyridine is changed from tridentate in the binary complex to bidentate in the ternary one where the uncoordinated pyridine exists in the protonated form. The dto and tsc act as neutral bidentate ligands coordinating through either sulfur or sulfur and nitrogen atoms respectively, forming chelate ring systems

Research Department
Research Journal
J. Therm. Anal. Cal.
Research Member
Research Publisher
Akadémiai Kiadó, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic Publishers B.V.
Research Rank
1
Research Vol
Vol 74 No. 3
Research Year
2003
Research Pages
pp , 801-810 .