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Tuneability and optimum functionality of plasmonic transparent conducting oxide-Ag core-shell nanostructures

Research Authors
Mohamed K. Zayed, Hesham Fares, Jamal Q.M. Almarashi, Samar Moustafa
Research Abstract

Tunning localized surface plasmon resonance (LSPR) in transparent conducting oxides (TCO) has a great impact
on various LSPR-based technologies. In addition to the commonly reported mechanisms used for tunning LSPR in TCOs (e.g., size, shape, carrier density modifications via intrinsic and extrinsic doping), integrating them in coreshell structures provides an additional degree of freedom to expand its tunability, enhance its functionality, and widen its versatility through application-oriented core-shell geometrical optimization. In this work, we explore
the tuneability and functionality of two TCO nanostructures; indium doped tin oxide (ITO) and gallium doped zinc oxide (GZO) encapsulated with silver shell within the extended theoretical Mie theory formalism. The effect of core and shell sizes on LSPR peak position and line width as well as absorption and scattering coefficients is numerically investigated. Simulations showed that LSPRs of ITO-Ag and GZO-Ag core-shell nanostructures have great tunning capabilities, spanning from VIS to IR spectral range including therapeutic window of human tissue
and essential solar energy spectrum. Potential functionality as refractive index sensor (RIS) and solar energy
absorber (SEA) are examined using appropriate figure of merits (FoM). Simulations indicate that a geometrically
optimized core-shell architecture with exceptional FoMs for RIS and SEA can be realized. Contrary to carrier
density manipulation, integrating TCO cores to metallic shells proves to be an effective approach to enhance
tunability and optimize functionality for high performance TCO-based plasmonic devices, with minimum impact
on the inherited physical and chemical properties of the used TCO-core materials.

Research Date
Research Department
Research Journal
Photonics and Nanostructures - Fundamentals and Applications
Research Publisher
Elsevier B.V.
Research Rank
Q2
Research Vol
62
Research Website
https://www.sciencedirect.com/science/article/pii/S1569441024001019
Research Year
2024
Research Pages
101326-101336